Sustainable Electrosynthesis: Radical Borylation with Cumulenes

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This presentation explores the innovative electroreductive borylation of chloroarenes utilizing single electron transfer (SET) methods, which have become pivotal in the field of organic synthesis. Traditional challenges with chloroarenes are overcome through the application of cumulene redox mediation, notably using Ph4-5-CML, which allows for high-yield borylation without light or additional reductants. The method demonstrates broad substrate compatibility, including electron-rich arenes,...